Lithium chloride complex, 1.3M solution in THF, AcroSeal .. Isopropylmagnesium chloride - Lithium chloride complex, 1.3M solution in THF, AcroSeal™, Thermo Scientific Chemicals ; CAS, 745038-86-2, 109-99-9 ; Molecular .Molecular Weight (g/mol): 145.234CAS: 745038-86-2, 109-99-9$119.40 · ‎30-day returnsPeople also askYou will see more English now.What is isopropylmagnesium chloride lithium chloride in THF?What is isopropylmagnesium chloride lithium chloride 1.3 m in THF?What is the use of iPrMgCl LiCl?What is a turbo Grignard?FeedbackIsopropylmagnesium chloride lithium .. Isopropylmagnesium chloride lithium chloride complex solution is a reagent used with CH3MgCl/LiCl to affect magnesium-halogen exchange on unprotected aryl .$99.00 · ‎In stockIsopropylmagnesium Chloride Lithium Chloride Complex .. Isopropylmagnesium Chloride- Lithium Chloride Complex Solution is one of numerous organometallic compounds manufactured by American Elements under the trade . Bluetooth Splitter Iphone, Isopropylmagnesium chloride lithium chloride complex .. Aldrich-656984; Isopropylmagnesium chloride lithium chloride complex solution 1.3 M in THF; Synonyms: Turbo Grignard; Linear Formula: (CH3)2CHMgCl · LiCl; .Reaction suitability reaction type: Grignard Rea.Molecular Weight: 145.24 Bluetooth Two Way Radios, Isopropylmagnesium chloride - LiCl complex 1.3 M in THF, .. Isopropylmagnesium chloride - LiCl complex 1.3 M in THF, AcroSeal™ ; MDL Number: MFCD07784514 ; CAS Number: 807329-97-1 ; UN: 3399 ; ADR: 4.3,I ; Appearance, Clear . Bluetooth Vs Optical, Magnesate(1-), dichloro(1-methylethyl)-, lithium. 807329-97-1, Magnesate(1-), dichloro(1-methylethyl)-, lithium, lithium;magnesium;propane;dichloride, MFCD07784514, iPrMgCl LiCl, . Compound CID: 11275082. Bluetooth Wooden Speakers, Progress and developments in the turbo Grignard reagent i .. by RLY Bao · 2015 · Cited by 168 — Over the past decade, the effectiveness of i-PrMgCl·LiCl has been constantly highlighted by a number of research groups. Its enhanced nucleophilicity brings . Bmw Bluetooth Update, 745038-86-2 | Isopropylmagnesium chloride lithium .. Isopropylmagnesium chloride lithium chloride complex solution - 1.3 M in THF - FI163187 ; CAS No. [745038-86-2] ; Synonyms. Turbo Grignard ; Product Code. FI163187.isopropylmagnesium chloride lithium chloride complex- .. · Translate this pagelithium chloro-isopropyl-magnesium chloride. CAS No. : 807329-97-1 Formula : C3H8Cl2LiMg Molecular Weight. : 146.248 Check Encyclopedia.Isopropylmagnesium chloride lithium chloride 1.3M .. A reagent commonly used with CH3MgCl/LiCl to affect magnesium-halogen exchange on unprotected aryl carboxylic acids.1 Applied for preparing reactive .Isopropylmagnesium chloride lithium chloride complex .. Isopropylmagnesium chloride lithium chloride complex solution 1.3 M in THF CAS 807329-97-1 WIKI information includes physical and chemical properties, USES, .Isopropylmagnesium chloride lithium chloride complex .. Isopropylmagnesium chloride lithium chloride complex solution, 1.3 M in THF · Synonyms: Turbo Grignard · Formula: C3H7Cl2LiMg · Formula Weight: 145.24 · Linear .30-day returnsIsopropylmagnesium chloride lithium chloride complex solution. Name:lithium chloro-isopropyl-magnesium chloride,CAS:807329-97-1.Molecular Fomula:C3H7Cl2LiMg,Molar Mass:145.24,Density:0.951 g/mL at 25 °C,Boling Point:66℃ . Bmw Remove Bluetooth Device, Isopropylmagnesium chloride lithium chloride complex. Jun 22, 2023 — Uses. Isopropylmagnesium chloride lithium chloride complex is a reagent for Selective Metalations. And it was used with CH3MgCl/LiCl to affect .Density: 1.05Color: Clear yellow to brown to gray Bocina Bluetooth Rca, Lithium chloride complex, 1.3M solution in THF, AcroSeal .. Isopropylmagnesium chloride - Lithium chloride complex, 1.3M solution in THF, AcroSeal™, Thermo Scientific Chemicals ; Quantity. 100 mL 800 mL ; Packaging.€112.00 to €316.00 · ‎Out of stock Bose Bluetooth Usb, Isopropylmagnesium chloride-Lithium chloride CAS 745038 .. Isopropylmagnesium chloride-Lithium chloride tetrahydrofuran solution is brown or dark red liquid，Molar concentration is 1.0~2.0M。 Application. Boxanne Bluetooth Speaker, Isopropylmagnesium chloride. Isopropylmagnesium chloride is also used to prepare other isopropyl compounds, such as chlorodiisopropylphosphine: . This reaction exploits the bulky nature of .CAS Number: 1068-55-9Molar mass: 102.84 g·mol−1 Breakaway Bluetooth Speaker, Supporting Information. PDFIsopropylmagnesium chloride/lithium chloride 1:1. (i-PrMgCl∙LiCl) in THF was from Chemetall GmbH. Gas chromatographic equipment:.One-Pot Selective Saturation and Functionalization of .. PDFby D Wang · 2020 · Cited by 9 — mmol), isopropylmagnesium chloride lithium chloride complex solution (1.1 ml, 1.3 M in THF, 1.45 mmol), TFAA (504 mg, 2.42.iso-Propylmagnesium Chloride / Lithium Chloride, typ. 14 .. PDFFeb 20, 2018 — iso-Propylmagnesium Chloride / Lithium Chloride, typ. . Isopropylmagnesium chloride. CAS-No. 1068-55-9. EC-No. 213-947-1. Lithium chloride.3 pagesSupporting Information. PDFTitration of the HMDS amidomagnesium chloride LiCl complex (HMDSMgCl⋅LiCl) in THF/toluene with COD . Yielding 88% of isopropylmagnesium chloride lithium.Continuous Flow Generation and Utilization of .. by T von Keutz · 2020 · Cited by 17 — Halogen–magnesium exchange in halomethanes is known to proceed at low temperatures with isopropylmagnesium chloride and with its lithium chloride complex.Isopropylmagnesium chloride-lithium chloride complex. Isopropylmagnesium chloride-lithium chloride complex. The product is for non-human research only. Not for therapeutic or veterinary use. Catalog Number: BT- .$305.38 · ‎In stock Callers Can't Hear Me On Bluetooth, Disposable Cartridge Concept for On-Demand Synthesis of .. PDFby M Berton · 2020 · Cited by 6 — most known example of this class is isopropylmagnesium chloride lithium chloride. *Data from SciFinder March 26, 2019. Edgewood Canada Goose, Process for the preparation of a pharmaceutical agent. Feb 23, 2017 — 0.75 ml (0.97 mmol) of isopropylmagnesium chloride/lithium chloride complex (turbo Grignard) solution (1.3 M solution in THF) was added and the . Camara Bluetooth, Lithium Dichloro(1‐methylethyl)‐magnesate - Knochel. by P Knochel · 2001 · Cited by 3 — Alternate Name: isopropylmagnesium chloride–lithium chloride complex. Physical Data: solution in THF, similar to the solvent. Cat Radio Bluetooth Pairing, Isopropylmagnesium chloride lithium chloride complex .. · Translate this pageIsopropylmagnesium chloride lithium chloride complex solutio. Vergleichen. MSDS. Artikel-Nr.: A0093938; CAS Nummer: 807329-97-1; Marke: Chemos. Charging Bluetooth, Buy Lithium Chloride. Buy and order Isopropylmagnesium chloride - Lithium chloride complex (CAS: 745038-86-2) at reasonable price from reliable supplier ABBLIS!Detailed information. Isopropylmagnesium chloride-lithium chloride complex, in tetrahydrofuran. 構造式画像. Price, ¥35,500. w/o tax. Stock：Contact us. Product No. 20344-05.¥35,500A. - Preparation of tmpMgCl·LiCl.. Then, tmpMgCl·LiCl (105 mL, 0.95 m in THF, 100 mmol, 1.1 equiv.) . iPrMgCl·LiCl: isopropylmagnesium chloride lithium chloride complex; (807329-97-1).Magnesium-Halogen Exchange | Myers. PDFIt is less soluble than the chloride (solutions are ~0.8 M), and the . Unlike many lithium-halogen exchange protocols, only one equivalent of i-PrMgX is .Desymmetrization Reactions of Indigo with Grignard Reagents .. PDFby N Butler · 2019 · Cited by 5 — Isopropylmagnesium chloride was initially selected as a model Grignard reagent . chloride lithium chloride complex) was prepared using isopropylmagnesium .Lithium chloride complex, 1.3M solution in THF, AcroSeal. · Translate this pageIsopropylmagnesium chloride - Lithium chloride complex, 1.3M solution in THF, AcroSeal® ; CAS: 745038-86-2 ; Chemical formula: C3H7Cl2LiMg .RUB 31,188.00 Christmas Tree With Bluetooth Speaker, Synthesis, Isolation, and Properties of All Head-to-Tail Cyclic .. by T Yamamoto · 2018 · Cited by 19 — iodothiophene (>97.0%, Tokyo Chemical Industry Co., Ltd.),. isopropylmagnesium chloride. –. lithium chloride. (. i. -. PrMgCl. ·. LiCl). Comfy Floats Bluetooth Speaker, 656984-100ML. · Translate this pageISOPROPYLMAGNESIUM CHLORIDE LITHIUM CHLORIDE COMPLEX, TETRAHYDROFURAN - Find MSDS or SDS, a COA, data sheets and more information. Como Conectar Mis Audifonos Bluetooth A Mi Tablet, Navigation. 7.6.14.2 Method 2: Synthesis of (2,2,6,6-Tetramethylpiperidino)magnesium Chloride–Lithium Chloride Complex. DOI: 10.1055 . Como Vincular Audifonos Bluetooth, Experimental Materials. Lithium chloride, .. PDFAddition of lithium chloride additive to isopropyl magnesium chloride enhances its reactivity. This type of very reactive Grignard reagent is known under . Craig Bluetooth Fm Transmitter, Lithium chloride complex, 1 3M solution in THF, AcroSeal¨ .. · Translate this pageIsopropylmagnesium chloride - Lithium chloride complex, 1 3M solution in THF, AcroSeal¨, 800 mL, ACROS ORGANICS®. Isopropylmagnesium chloride - Lithium .Chem. Pharm. Bull. 59(6): 797-798 (2011). by M Kogami · 2011 · Cited by 3 — Isopropylmagnesium chloride solution was added to 3 in the presence of LiCl for 1.5 h at ambient temperature, and then the mixture was gradually warmed to .745038-86-2 | Isopropyl magnesium chloride-lithium chloride. Hangzhou Keying Chem Co., Ltd. Cas 745038-86-2,Isopropyl magnesium chloride-lithium chloride;KY141493.Isopropylmagnesium chloride lithium .. Isopropylmagnesium chloride lithium chloride complex solution, CAS 807329-97-1 available from Santa Cruz Biotechnology at SZABO-SCANDIC.Grignards on lithium - The chemical reaction database. Oct 15, 2008 — The (now commercial Link) THF solution of isopropylmagnesium chloride with lithium chloride (CAS 807329-97-1) is sometimes called a .Isopropylmagnesium chloride li | 656984-4X25ML. Isopropylmagnesium chloride lithium chloride complex solution, 1.3 M in THF . Reagent for Selective MetalationsUsed for: Preparation of functionalized acyclic .€111.67 Delphi Radio Bluetooth Pairing, Improving the Halogen‐Magnesium Exchange by Using .. It shows that the use of turbo‐Grignard reagent (iPrMgCl·LiCl) greatly enhances the rate of the Br‐ and I‐Mg exchange. Furthermore, this magnesium reagent . Escape Outdoors Canada Goose, Isopropylmagnesium chloride-lithium chloride complex. Buy Isopropylmagnesium chloride-lithium chloride complex (CAS No. 745038-86-2) from Smolecule. Molecular Formula: C3H7Cl2LiMg. Molecular Weight: 145.3 g/mol . Rating: 4.5 · ‎9 votes Denon Avr-x2100w Bluetooth Pairing, SynQuest Labs, Inc.. Product #: 9112-5-04 ; Synonyms: Turbo Grignard ; CAS Number: 745038-86-2 ; MDL Number: MFCD07784514 ; Molecular Formula: C₃H₇Cl₂LiMg. Discus Bluetooth, Isopropylmagnesium chloride lithium .. · Translate this pageIsopropylmagnesium chloride lithium chloride complex solution. データシート. CAS RN®, 807329-97-1. その他, [性状]1.3 M in THF. メーカー, 品番, 包装. Dj Mixer With Bluetooth, Substance Information - ECHA - European Union. Dec 21, 2021 — Isopropylmagnesium chloride lithium chloride complex. IUPAC names 2 Other identifiers 1.Isopropylmagnesium chloride lithium chloride complex. Isopropylmagnesium chloride lithium chloride complex · Formula C3H7Cl2LiMg · Molecular Weight145.24 · MDL number MFCD07784514 · PubChem Substance ID 11275082 .¥193友購快. · Translate this pageIsopropylmagnesium chloride lithium chloride complex solution 1.3 M in THF. NT$4,400. 品牌:ALDRICH 品號:656984 品名:異丙基氯化鎂-氯化鋰複合溶液規格:100ML.NT$4,400.00TR-I874643 - Isopropylmagnesium Chloride Licl Complex .. Isopropylmagnesium chloride lithium chloride complex is an organic compound that is used as a reagent … Formula: C3H7Cl2LiMg. Purity: Min .CAS: 745038-86-2Molecular weight: 145.24 g/mol异丙基氯化镁-氯化锂结构式 - 物竞化学品数据库. · Translate this page异丙基氯化镁-氯化锂Isopropylmagnesium chloride - Lithium chloride complex · 编号系统. CAS号：745038-86-2 · 物性数据. 1. 性状：无可用 · 毒理学数据. 暂无 · 生态学数据.CAS#:745038-86-2 | isopropylmagnesium chloride-lithium .. Jan 2, 2023 — isopropylmagnesium chloride-lithium chloride complex ; Molecular Weight, 145.24000 ; Density, 1.05 ; Boiling Point, N/A ; Molecular Formula, C3H7Cl2 . Efm Toledo Bluetooth Speaker, Isopropylmagnesium chloride li | 656984-100ML. Isopropylmagnesium chloride lithium chloride complex solution, 1.3 M in THF . Reagent for Selective MetalationsUsed for: Preparation of functionalized acyclic .£90.40 Elf Bluetooth Earbuds, Explore our newly expanded range of Grignard Reagents. PDFBenzylmagnesium chloride, 1M solution in diethyl ether, AcroSeal . Isopropylmagnesium chloride - lithium chloride complex, 1.3M solution in THF, AcroSeal. Everleigh Canada Goose, 中文名称：异丙基氯化镁-氯化锂. · Translate this page品名：Isopropylmagnesium chloride lithium chloride complex solution · 品名_中文：异丙基氯化镁-氯化锂 · 品牌：macklin · 货号：I812121-1L · 包装规格：1L · casno： .¥825 Ford Bluetooth, 745038-86-2|Isopropylmagnesium Chloride. Product Name: Isopropylmagnesium Chloride - Lithium Chloride Complex ; Synonyms: ; Catalog No.: S214221 ; CAS No.: 745038-86-2 ; MDL No.: MFCD07784514 . Furrion Bluetooth, GRIGNARD REAGENTS | Pioneer in Bromine and Lithium .. Methyl magnesium chloride 3M in THF . iso-propyl magnesium chloride Lithium chloride complex . isopropyl magnesium bromide 1M in THFLiCl-Mediated Direct Insertion of Magnesium Into Aryl, .. PDFby FM Piller · 2010 — Magnesium Insertion in the Presence of LiCl Into Aryl and Heteroaryl . A CuCN·2 LiCl-mediated acylation31 with 4-chlorobenzoyl chloride.Supporting Information. PDFby HH Liua · Cited by 2 — 1.3 M isopropylmagnesium chloride lithium chloride complex (0.25 mL, 0.32 mmol) diluted by dried THF (8 mL) was added dropwisely a solution of SSeI2 (200 mg .ISOPROPYLMAGNESIUM CHLORIDE LITHIUM CHL&. · Translate this pageISOPROPYLMAGNESIUM CHLORIDE LITHIUM CHL&. SKU: 656984-4X25ML. Salīdzināt · Drošības datu lapa. Isopropylmagnesium chloride lithium chloride complex solution .Isopropylmagnesium chloride-lithium chloride complex. Isopropylmagnesium chloride-lithium chloride complex (IPMCL-LiCl) is a complex of two organometallic compounds, isopropylmagnesium chloride and lithium chloride .Isopropylmagnesium chloride-lithium chloride complex. Isopropylmagnesium chloride-lithium chloride complex is an organometallic reagent used as a catalyst for various organic reactions. Furrion Dv7200 Bluetooth Pin, Common Pyrophoric and Water-Reactive Chemicals at .. PDFH250 H251 H260 H261 HNOC H220. WHITE PHOSPHORUS (PHOSPHORUS TETRAMER). 12185-10-3. X. TITANIUM (II) CHLORIDE. 10049-06-6. X. LITHIUM. 7439-93-2. Gallstep Bluetooth Speaker Instructions, Isopropylmagnesium chloride, Lithium .. Isopropylmagnesium chloride, Lithium chloride complex, 1.3M in THF, AcroSeal? ; Brand · Acros Organics ; Country of Origin · Belgium ; CAS Number · 745038-86-2 ; CAS .HK$1,270.50 Gmc Acadia Bluetooth Problems, Images for isopropylmagnesium chloride lithium chloride. ISOPROPYLMAGNESIUM CHLORIDE-LITHIUM CHLORIDE COMPLEX 745038-86-2;807329-97-1 ; CCD No. CCD00611432 ; Product Name, ISOPROPYLMAGNESIUM CHLORIDE-LITHIUM CHLORIDE . Gp-pwm-30-ul Bluetooth, Isopropylmagnesium Chloride Lithium .. Isopropylmagnesium Chloride Lithium Chloride Complex Solution, 1.3 M in THF, by Sigma-Aldrich, Certified, 100ml (Hazmat Fee Included).$115.00 · ‎14-day returns Gpx Bluetooth Boombox, 807329-97-1. Formula: C3H7Cl2LiMg ; Molecular Weight:145.24 ; Synonyms: isopropylmagnesium chloride lithium chl&. isopropylmagnesium chloride lithium chloride complex solution.Aryl Grignard Reagents (Update 2010) - H. Yorimitsu. PDFSince the discovery of isopropylmagnesium chloride–lithium chloride complex (1) as an extremely powerful reagent for halogen–magnesium exchange, .LITHIUM CHLORIDE COMPLEX for Sale from . - ECHEMI. ECHEMI supplies 16 top grade ISOPROPYLMAGNESIUM CHLORIDE - LITHIUM CHLORIDE COMPLEX products from 12 reliable manufactures. 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Neobits.com: Buy Sigma Aldrich / Merck - 656984-800ML - Isopropylmagnesium chloride lithium chloride complex solution.$415.00 · ‎15-day returns Honda Pilot Bluetooth, CASNO 745038-86-2 ISOPROPYLMAGNESIUM CHLORIDE. ISOPROPYLMAGNESIUM CHLORIDE - LITHIUM CHLORIDE COMPLEX · Suppliers of above Chemical · +91-95539-69696 · MEMBERSHIP · Advertise · LPG Apps Store · Windows Apps Store . Hot Tub With Bluetooth Speakers And Lights, Isopropylmagnesium chloride. PDFMSDS Name: Isopropylmagnesium chloride - Lithium chloride complex solution in THF. Catalog Numbers: AC386280000, AC386281000, AC386288000. Synonyms: None Known. Hyundai Bluetooth Problem, 807329-97-1 suppliers and producers. Synomyme names of CAS number · Iso-propylmagnesium chloride / lithium chloride · Isopropylmagnesium chloride lithium chl& · Isopropylmagnesium chloride lithium .745038-86-2 | Isopropyl magnesium chloride lithium .. Capot Chemical CAS# 745038-86-2, Isopropyl magnesium chloride lithium chloride. 745038-86-2 MSDS,ROS,745038-86-2 MOA,COA,SPECS,pecifications,1H-NMR,GHS,CAT .Turbo-Grignard™ Isopropylmagnesium Chloride. Your Position: Home > highlight > Turbo-Grignard™ Isopropylmagnesium Chloride –Lithium Chlorid. Phone : 1-302-525-4060How to Write the Net Ionic Equation for AgNO3 + LiCl = LiNO3 .. 3:07There are three main steps for writing the net ionic equation for AgNO3 + LiCl = LiNO3 + AgCl (Silver nitrate + Lithium chloride).YouTube · Wayne Breslyn · Apr 22, 20204 key moments in this videoIsopropylmagnesium chloride lithium .. · Translate this pageFeb 21, 2018 — Isopropylmagnesium chloride lithium chloride complex solution.Lithium chloride Importer Data in India. DateIndian PortCTHQuantityUQCU.P.USDAssess USDC O O22‑Nov‑2016banglore air cargo293190902NOS69.61139.21germa.21‑Nov‑2016bombay air cargo282739902PCS289.25578.50germa.21‑Nov‑2016hyderabad air cargo28273990100GMS0.1110.53united.View 7 more rows Goose Down Duvet Canada, Isopropylmagnesium Chloride LiCl Complex (1.3M in THF) .. Isopropylmagnesium Chloride LiCl Complex (1.3M in THF), 500ml · Brand: Toronto Research Chemicals · Catalog No.: I874643-500ml · CAS No: 745038-86-2 · Quantity/Unit . Insignia - Bluetooth Stereo Turntable - Black, How to Write the Net Ionic Equation for MgCl2 + Li2CO3 = LiCl .. 2:57There are three main steps for writing the net ionic equation for MgCl2 + Li2CO3 = LiCl + MgCO3 (Magnesium chloride + Lithium carbonate).YouTube · Wayne Breslyn · Jul 30, 2020 Ion Explorer Speaker Bluetooth, Lithium chloride complex, 1.3M solution in THF, AcroSeal. Isopropylmagnesium chloride – Lithium chloride complex, 1.3M solution in THF, AcroSeal . Send out an enquiry for this chemical/service. By filling out the form . Ion Explorer Xl Bluetooth Speaker, Isopropyl Magnesium Chloride/Lithium Chloride 1.3M in THF. Isopropyl Magnesium Chloride/Lithium Chloride 1.3M in THF in Hyderabad offered by Sainor Pharma Pvt Ltd. Get Best Price, MOQ for Isopropyl Magnesium . Rating: 3.6 · ‎20 votes Iphoenix Bluetooth Speaker, Isopropylmagnesium Chloride Lithium .. Isopropylmagnesium Chloride Lithium Chloride Complex, for Industrial, Purity : 99.9%. by Jay Chem Marketing, Mumbai. Call Now. Get Latest Price. Product Details.Import Data and Price of isopropylmagnesium chloride. DateHS CodeOrigin CountryPort of DischargeUnitQuantityValue (INR)Per.Nov11201629319090United StatesBanglore Air CargoNOS17,1917,191Nov05201629319090United StatesBanglore Air CargoNOS119,54119,5.Oct28201629319090United StatesBanglore Air CargoNOS675,15012,5.View 17 more rowslithium dichloro(1-methylethyl)-magnesate | C3H7Cl2LiMg. More details: · Systematic name. Lithium chloride - chloro(isopropyl)magnesium (1:1:1) · SMILES. [Li+].CC(C)[Mg]Cl.[Cl-] · Std. InChi. InChI=1S/C3H7.2ClH.Li.Mg/c1- .Handbook of Reagents for Organic Synthesis: Reagents for .. André B. Charette · 2015 · ‎ScienceIts reactivity far exceeds the reactivity of i-PrMgCl–LiCl, so that it can . Isopropylmagnesium chloride–lithium chloride is a very convenient reagent for .Directory of Lithium chloride Buyers & importers in India. Jun 4, 2023 — Choose New & profitable buyers from 140 Lithium chloride importers in India based on import shipments till Jun - 23 with Price, Supplier, . Jensen Bluetooth Pairing Code, Lithium Chloride Suppliers USA. Cas No. 7447-41-8. EC Number: 231-212-3. IUPAC Name: lithium; chloride. Molecular Formula: LiCl . Jensen Jdvd1500 Bluetooth Pairing, Turbo Grignard Reagent. Jan 10, 2015 — The addition of one equivalent of lithium chloride when preparing Grignard reagents accelerates both the metal-halogen exchange and the .